Newtonian and Non-Newtonian Fluids, Water Hammering, and Cavitation in Pumps
While handling pumping systems, it is critical to have a background understanding of some of the important concepts that govern pump performance, efficiency, output, and longevity. The following resource aims to discuss the concepts of Newtonian/Non-Newtonian fluids, water hammering, cavitation in pumps, and how these factors impact modern pumping systems.
Newtonian and Non-Newtonian fluids
In fluid pumping, it is fairly important to understand the properties of the fluids being pumped, transferred, and mixed. This understanding plays a major role in selecting suitable equipment for fluid pumping. Fluid viscosity or thickness determines the way a particular fluid will behave in a pump. When it comes to fluid viscosity, fluids show a non-uniform pattern. Some fluids maintain a constant viscosity while others show a significant change in viscosity as temperature and applied forces change.
In general, fluids can be divided into two broad categories. Newtonian fluids and Non-Newtonian fluids. Non-Newtonian fluids have further subcategories (more on that later). Pump manufacturers and end-users must have a clear understanding of these fluid types and their behavior. This plays a vital role while selecting and operating pumps.
Understanding ‘Shear’
Before we move on, it is important to understand the concept of ‘shear’. In very simple terms, shear is the relative motion between adjacent layers of a fluid that is in motion. An example of a fluid in motion is when butter is applied to bread. In this case, there is relative motion between two layers of fluid (butter on the knife and butter on the bread).
In the case of solids, the shear force acts tangentially to the surface of the solid. A solid can resist deformation due to this force but a fluid will flow under its influence. When adjacent layers of a fluid move relative to each other, shear stresses are developed. Shear forces are developed because adjacent layers of a fluid move with different velocities in a pipe (thus there is relative motion between them). Shear rate is defined as a measure of the extent of this relative motion between the layers.
Newtonian Fluids
Newton’s law states that the shear stress is directly proportional to shear rate when fluid viscosity is constant. Fluids obeying this law are called Newtonian fluids. In other words, the fluid viscosity does not change no matter how much shear is experienced by it. In the case of Newtonian fluids, kinematic viscosity is considered. This is the viscosity when no external forces are acting on the fluid. In other words, this is the viscosity when only gravity is acting upon a fluid. The kinematic viscosity of Newtonian fluids remains constant even if external forces are applied to the fluid. Examples of such fluids include water, high viscosity fuel, some motor oils, most mineral oils, gasoline, kerosene, most salt solutions in water, light suspensions of dye stuff, kaolin (clay slurry). These fluids have fairly defined and consistent flow characteristics.
Non-Newtonian Fluids
The viscosity of these fluids changes as shear is applied. This makes them much more challenging to pump. In the case of Non-Newtonian fluids, the Dynamic viscosity is considered and it changes when shear is experienced by the fluid. During pump design, the changing viscosity has to be considered for ensuring appropriate flow, pipe size, and optimum pump characteristics (pump speed; inlet pressure requirements; pump pressure drop to initiate flow). Depending upon how the viscosity changes in response to external forces, Non-Newtonian fluids are further divided into sub-categories. These categories are as follows:
Dilatant
The fluid viscosity increases as shear is applied. They are also called shear thickening. If you quickly try to force an object through such a fluid, it will be met with a lot of resistance. On the contrary, slowly introducing the object will give its molecules the time to move away and the object will move while facing much less resistance. Examples of such liquids include:
- Feldspar
- Quicksand
- Beach sand
- Clay
- Mica
- Silly putty
Pseudoplastic
In the case of pseudoplastics, viscosity decreases when shear is applied. Examples of such cases are:
- Grease
- Soap
- Sewage
- Sludge
- Molasses
- Paint
- Most emulsions
- Paper pulp
- Printer’s ink
- Starch
Figure 1: Stress response of dilatants and pseudoplastics
Thixotropic
In addition to shear, the viscosity is also time-dependent in the case of thixotropic fluids. The application of shear decreases the viscosity and the viscosity also decreases as time goes by. These fluids include:
- Silica gel
- Greases
- Bentonite
- Inks
- Mayonnaise
Rheopectic
The behavior of these fluids is similar to dilatants (viscosity increases with shear) but the difference is that the viscosity is time-dependent as well as goes on to increase with time. Examples include
- Gypsum in water
- Asphalt
- Lard
- Starch
- Fruit juice concentrates
- Molasses
Figure 2: Stress response of Rheopectic and thixotropic fluids
Shear thickening in Non-Newtonian fluids
Under a fast-moving shear force, shear thickening fluids tend to act like solids. The more force is increased, the more their viscosity increases. When pumps are run at high speeds, they produce high pressure as well as fast-moving shear forces. This increases the viscosity of these fluids because the molecules crowd each other under high pressure. On the contrary, molecules have time to move out of each other’s way under low pressure and low velocities which causes a decrease in viscosity. It means that the pump speed and pressure greatly influence the way fluids behave during processing and dispensing.
A Non-Newtonian fluid tends to resist flow much more than a Newtonian fluid like water. This difference in viscosity has to be taken into account to maximize production efficiency. Viscosity affects how long fluid takes to dispense and its flow rate. Besides viscosity, shear thickening also needs to be considered (it is a fluid’s response to shear forces). For example, ketchup is a shear-sensitive fluid and at rest doesn’t pour well. But in response to squirting (application of forces), it becomes less viscous and pours easily out of the bottle. Honey is not a shear sensitive fluid so squeezing a honey bottle doesn’t affect its viscosity considerably. For pump and piping systems designers, this is important to consider because shear-sensitive fluids like shampoo, ketchup, or egg white need to be handled gently as their composition and integrity can be affected.
Shear thickening in pumps
As discussed earlier, Non-Newtonian shear-sensitive fluids change in viscosity in response to shear. This means that while passing through the impeller of a pump, the fluid viscosity changes in response to forces exerted by the impeller. Shear thickening fluids (dilatants) increase in viscosity while the viscosity of shear-thinning fluids decreases when forces are applied. Corn starch, for example, is a dilatant, and its viscosity increases when a mixture of cornstarch and water flows out of a pump.
Why are high efficiency pumps important?
Pump efficiency is the ratio of the amount of fluid entering the pump to the amount of fluid leaving it. A pump with higher pump efficiency is more effective for gentle product handling. A low-efficiency pump means that some portion of the product remains in the pump casing and is recirculated. This further impacts the fluid’s viscosity and sometimes the changes in viscosity can be permanent due to overhandling which can result in compromising the product’s integrity.
To avoid this problem, a positive displacement pump can be used. Such a pump can deliver a constant flow rate at a given pump speed. Even if the viscosity increases, a constant rate of the fluid can be dispensed by ramping up the pump’s horsepower.
Water Hammer and its causes
Water hammer is a surge of pressure that can arise in pumping systems. The pressure is created when the pumping system undergoes an abrupt change in flow. The main causes of water hammering include opening and closing of valves, pump starts and stops, and separation and closure of the water columns. Due to these factors, the water column undergoes a change in momentum and this abrupt change can produce shock waves that travel back and forth within the system. Depending on the magnitude of the shock wave, physical damage in the system can be severe. The phenomenon can be understood by an example in which water is pumped in a pipe that has valves on its both ends. The inlet valve is opened and the water column starts traveling towards the discharge valve. At this point, the discharge valve is closed instantly and the leading edge of the water column strikes the closed valve and begins to compress. A pressure wave (shock wave) begins to travel along the backstream (towards the inlet valve). The shock wave travels back and forth between the two valves until it finally diminishes due to friction losses. This water hammer shock wave is so fast that it can make a round trip between the two valves in less than half a second in the case of a 1000 feet pipe. The pressure created by this shock wave depends on the wave velocity (a), the velocity of water in the pipe (V), and the universal gravitational constant (g). Mathematically,
P = a V / 2.31 g
Even at a pipe velocity of just 10 ft/sec, the additional pressure can reach 657 psi. This is a huge amount of pressure that can easily devour pipelines!
Causes of water hammer
If we examine the causes of this phenomenon, there appear to be three dominant factors:
- Valve opening and closure
- Pump start and stops
- Water column separation and closure
Valve opening and closure
The abrupt closure of valves is one of the primary causes of water hammer. Consider the system in figure 3 below. A branch is feeding the main pipeline and the circuit is in the form of a ‘Tee’. A valve has been installed at the end of the branch. In this case, the primary barrier to water flow is the valve while the secondary barrier is the ‘Tee’.
If the valve is closed quickly when the water is flowing in the branch line, a shock wave will develop and will travel back and forth between the valve and the Tee. The time of valve closure (i.e. how quickly the valve is closed) also affects the intensity of the water hammer. The following equation gives the relationship between the additional pressure generated by the shock wave (P), flow velocity in ft/sec (V), pipe length between barriers (P), and valve closing time in seconds (t):
P = 0.07 (VL / t)
The additional pressure is directly related to the flow velocity and length of the pipe between the barriers. It is inversely related to the valve closure time. Since the pipe length is often fixed, the additional pressure caused by the water hammer can be managed by changing the valve closure timing and the flow velocity.
It is also important to know that water hammering can have more devastating effects in systems designed to operate at low pressures. A 1000 ft pipe with a 5 ft/s flow velocity will experience the same intensity of shockwave whether operating at a pressure of 50 psi or operating at a pressure of 200 psi. The main difference is that the ratio of shock pressure to design pressure will be much higher for a system with a 50 psi design pressure than for a system with a 200 psi design pressure. The damage in the case of the 50 psi system will, therefore, be much greater.
Pump starts and stops
When a pump is started in large pumping systems, it is done so when the discharge valve is closed. The valve is opened slowly only after the pump has reached its maximum speed. Water hammer is significantly reduced when the pumps are started and stopped against a valve that is opened or closed slowly.
The problem occurs when the pump motor loses power during a power outage. This reduces the water flow at pump discharge and a water hammer is created due to abrupt changes in pressure and kinetic energy of the flowing water. This shockwave can reverse the water direction that can prompt the pump impeller to accelerate in the reverse direction. This creates additional pressure because backflow is reduced when the impeller reaches maximum reverse speed.
To mitigate this situation, a ‘spring-loaded’ check valve is installed at the pump discharge and a specific value of pressure is maintained at the pump inlet. When the pump starts, it has to create more pressure than that at the pump inlet in order for the flow to initiate. This ensures that the flow is increased gradually and water hammering is not initiated. When the pump stops, the spring-loaded valve is instantly closed. This prevents the water column from changing direction and a relatively uniform pressure is maintained through the pipeline.
If a normal check valve is used instead of a spring-loaded one, the water column will accelerate backward and slam the check valve close thus initiating a shock wave.
Water column closure and separation
This occurs in a two-phase system when the water column exists as liquid and vapor simultaneously. When the pressure in the pipeline is reduced below the vapor pressure of water, a phase change can occur. This can separate portions of the liquid water column by creating pockets of water vapor in between. When the pressure rises and exceeds vapor pressure, the liquid water column joins again (water column closure) that can create a wave of high pressure. This is how water column closure and separation can cause damage to thin-walled pipes.